The ability of cationized dialdehyde cellulose to improve the mechanical properties of paper was evaluated. The majority of cationized additives are synthesized by introducing cationic groups through chemical reactions. Here, cationized additives were produced in a more environmentally friendly manner by use of non-toxic and readily biodegradable deep eutectic-like solvent mixtures (DESs). The modified cellulose’s properties were characterized by FTIR, polarized-light optical microscopy, charge titrations, and SEM/EDX. The cationized additives were investigated as strength additives for papermaking. Three different amounts of cationic additive (2%, 5%, and 10%) were added to the pulp, and the properties of handsheets were studied. Because increasing the additive content can affect dewatering of the process, the dewatering capabilities of the pulps with additives were evaluated by Schopper-Riegler (°SR) value, water retention value (WRV), and vacuum dewatering. Finally, the recyclability of the DES was assessed in terms of cationization reaction efficiency and their effect on paper mechanical properties.

Hornification, a complex phenomenon occurring during drying of lignocellulosic materials because of formation of irreversible chemical bonds, remains a subject of scientific interest. This study aims to shed light on the underlying mechanisms of hornification by investigating interactions between the liquid and solid phases through a solvent exchange treatment. The treatment involved replacing water with various solvents in suspensions of never-dried cellulose samples, including alcohols (methanol, ethanol, isopropanol) capable of forming hydrogen bonds, albeit to a lesser extent than water, as well as non-alcohol solvents (acetone, ethyl acetate, toluene, heptane) that do not possess the ability to form chain of hydrogen bond, and no hydrogen bond between each other. The impact of solvents on the hornification process was evaluated using WRV measurements. Our findings reveal that water, as a solvent, plays a dominant role in the hornification process, primarily due to its excellent capability to form bridges of hydrogen bonds. In comparison, hornification with alcohols was considerably lower than with water, likely attributed to the smaller ability of alcohols to engage in such interactions. Furthermore, our results indicate a tendency for reduced hornification also when using non-hydrogen bond solvents with decreased polarity. This strengthens the hypothesis related to chains of hydrogen bonds. Additionally, the interaction between hydrophobic surfaces on cellulose through hydrophobic interactions could provide another plausible explanation.

In the manufacturing of cellulose derivatives, improving cellulose accessibility is essential for achieving a high product quality. In this study, endoglucanase enzyme treatment was applied prior to the cationization reaction to enhance the accessibility of hydroxyl groups for the production of cationized dialdehyde cellulose (CDAC). A range of enzyme dosages (0.09–45.00 ECU/g) was tested, and their effects on the swelling behavior and surface charge density of the final product were evaluated. The surface charge density of the ultimate cellulosic derivative confirmed its cationization and was proven to enhance the charge density of cationized dialdehyde cellulose (35% increase) compared to untreated pulp with enzyme. Additionally, the modified cellulose exhibited a significantly higher swelling capacity than regular pulps. These findings suggest that enzymatic pretreatment can enhance fiber reactivity and support a more sustainable and efficient production of cellulose-based derivatives, offering a promising potential for commercial applications.