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  • 1. Bohlin, Christina
    In vitro and in vivo oxidation of diastereomers of lignin models of arylgylcerol b-aryl ether type and heterologous expression of laccase2008Doctoral thesis, monograph (Other academic)
  • 2.
    Bohlin, Christina
    et al.
    Karlstad University, Faculty of Technology and Science, Department of Chemistry and Biomedical Sciences.
    Jönsson, Leif J
    Karlstad University, Faculty of Technology and Science, Paper Surface Centre.
    Lundquist, K
    Oxidation of the erythro and threo forms of the phenolic lignin model compound 1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)-1,3-propanediol by laccases and model oxidants2009In: Bioorganic chemistry (Print), ISSN 0045-2068, Vol. 37, no 5, p. 143-148Article in journal (Refereed)
    Abstract [en]

    Mixtures of equal amounts of the erythro and threo forms of the phenolic arylglycerol β-aryl ether 1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)-1,3-propanediol were oxidized (i) with laccases from Trametes versicolor, Agaricus bisporus, Myceliophthora thermophila and Rhus vernicifera, (ii) with laccase-mediator systems consisting of T. versicolor laccase and ABTS or HBT, and (iii) with various model oxidants including cerium(IV) ammonium nitrate (CAN), lignin peroxidase, Fenton’s reagent, and lead(IV) tetraacetate (LTA). All the laccases exhibited a similar preferential degradation of the threo form. The mediator ABTS counteracted the threo preference of laccase, but the mediator HBT did not affect it. The outer-sphere model oxidants CAN and lignin peroxidase showed a preferential degradation of the threo form. LTA and Fenton’s reagent did not exhibit any stereo-preference. The results suggest that laccases of different origin, primary structure, and redox potential behave as typical outer-sphere oxidants in their interaction with the diastereomers of the arylglycerol β-aryl ether

  • 3.
    Bohlin, Christina
    et al.
    Karlstad University, Faculty of Technology and Science, Department of Chemistry and Biomedical Sciences.
    Lundquist, Knut
    Forest Products and Chemical Engineering, Department of Chemical and Biological Engineering, Chalmers Univeristy of Technology.
    Jönsson, Leif J.
    Karlstad University, Faculty of Technology and Science, Department of Chemistry and Biomedical Sciences.
    Diastereomer selectivity in the degradation of a lignin model compound of the arylglycerol β-aryl ether type by white-rot fungi2008In: Enzyme and microbial technology, ISSN 0141-0229, E-ISSN 1879-0909, Vol. 43, no 2, p. 199-204Article in journal (Refereed)
  • 4.
    Bohlin, Christina
    et al.
    Karlstad University, Faculty of Technology and Science, Department of Chemistry and Biomedical Sciences.
    Lundquist, Knut
    Forest Products and Chemical Engineering, Department of Chemical and Biological Engineering, Chalmers University of Technology.
    Jönsson, Leif J.
    Karlstad University, Faculty of Technology and Science, Department of Chemistry and Biomedical Sciences.
    Oxidation of the erythro and threo forms of the phenolic lignin model compound 1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)-1,3-propanediol by laccases and model oxidantsManuscript (Other academic)
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