INFLUENCE OF DEPOSITION CONDITIONS ON MICROSTRUCTURE AND TEXTURE OF Ti1-XAlXN PVD COATINGSShow others and affiliations
2024 (English)In: NANOCON Conference Proceedings - International Conference on Nanomaterials, TANGER Ltd. , 2024, p. 112-117Conference paper, Published paper (Refereed)
Abstract [en]
This study is focused on how the application of pulsed substrate bias during cathodic arc deposition affects the microstructure, texture, grain size and phase composition of (Ti,Al)N coatings. A series of Tix-1AlxN, 0.25≤x≤0.55 coatings were deposited on WC-Co cemented carbide substrates with -30 V, -60 V and -300 V pulsing bias (duty cycle 10 % and a frequence of 1 kHz) under controlled chamber conditions at 4.5 Pa N2-gas and a substrate temperature about 400 °C. The pulsing parameters for the bias (voltage, duty cycle and frequency) were deliberately selected to influence structure, microstructure and composition of the deposited coatings. All Tix-1AlxN coatings had a consistent columnar cubic B1 structure regardless of their chemical composition. Coatings grown at -30 V and -60 V pulsed bias exhibited a pronounced <111> texture attributed to a kinetically driven mechanism influenced by the relative flux of ion species, affecting the surface migration of adatoms during growth. In contrast, the coatings grown with a pulsed bias of -300 V exhibited a reduced <111> texture and the onset of grains with <100> preferred orientation. The transition to the <100> orientation with increased ion energy agrees with the fact that the <111> directions expose the densest array of atoms to the ion beam during growth while the <100> are the most open channeling directions in a B1 structure. The correlation to the preferred with respect to pulsing conditions during growth, correlated to microstructure, grain size and phase composition be further discussed. Surface roughness was highest (Sa≈0.17-0.22 µm) for coating deposited at pulsed bias -30 V.
Place, publisher, year, edition, pages
TANGER Ltd. , 2024. p. 112-117
Keywords [en]
Aluminum coatings, Aluminum compounds, Carbides, Cobalt compounds, Grain size and shape; Ion beam assisted deposition, Ion beams, Ions, Nanostructured materials, Phase composition, Structure (composition), Substrates, Textures, Titanium compounds, Cathodic arc deposition, Deposition conditions, Duty-cycle, Grainsize, Microstructure-texture, Pulsed bias, Substrate bias, Ti-Al-N, Tix-1alxn coating, WC Co cemented carbide substrate, Surface roughness
National Category
Manufacturing, Surface and Joining Technology
Research subject
Mechanical Engineering; Materials Engineering
Identifiers
URN: urn:nbn:se:kau:diva-99735DOI: 10.37904/nanocon.2023.4755Scopus ID: 2-s2.0-85191190712ISBN: 978-80-88365-15-0 (electronic)OAI: oai:DiVA.org:kau-99735DiVA, id: diva2:1864176
Conference
15th International Conference on Nanomaterials - Research and Application, NANOCON, Brno, Czech Republic, October 18-20, 2023.
Funder
Knowledge Foundation2024-06-032024-06-032024-06-03Bibliographically approved