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INFLUENCE OF DEPOSITION CONDITIONS ON MICROSTRUCTURE AND TEXTURE OF Ti1-XAlXN PVD COATINGS
Karlstad University, Faculty of Health, Science and Technology (starting 2013), Department of Engineering and Physics (from 2013).
Karlstad University, Faculty of Health, Science and Technology (starting 2013), Department of Engineering and Physics (from 2013).
Seco Tools AB, Sweden.
Seco Tools AB, Sweden.
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2024 (English)In: NANOCON Conference Proceedings - International Conference on Nanomaterials, TANGER Ltd. , 2024, p. 112-117Conference paper, Published paper (Refereed)
Abstract [en]

This study is focused on how the application of pulsed substrate bias during cathodic arc deposition affects the microstructure, texture, grain size and phase composition of (Ti,Al)N coatings. A series of Tix-1AlxN, 0.25≤x≤0.55 coatings were deposited on WC-Co cemented carbide substrates with -30 V, -60 V and -300 V pulsing bias (duty cycle 10 % and a frequence of 1 kHz) under controlled chamber conditions at 4.5 Pa N2-gas and a substrate temperature about 400 °C. The pulsing parameters for the bias (voltage, duty cycle and frequency) were deliberately selected to influence structure, microstructure and composition of the deposited coatings. All Tix-1AlxN coatings had a consistent columnar cubic B1 structure regardless of their chemical composition. Coatings grown at -30 V and -60 V pulsed bias exhibited a pronounced <111> texture attributed to a kinetically driven mechanism influenced by the relative flux of ion species, affecting the surface migration of adatoms during growth. In contrast, the coatings grown with a pulsed bias of -300 V exhibited a reduced <111> texture and the onset of grains with <100> preferred orientation. The transition to the <100> orientation with increased ion energy agrees with the fact that the <111> directions expose the densest array of atoms to the ion beam during growth while the <100> are the most open channeling directions in a B1 structure. The correlation to the preferred with respect to pulsing conditions during growth, correlated to microstructure, grain size and phase composition be further discussed. Surface roughness was highest (Sa≈0.17-0.22 µm) for coating deposited at pulsed bias -30 V. 

Place, publisher, year, edition, pages
TANGER Ltd. , 2024. p. 112-117
Keywords [en]
Aluminum coatings, Aluminum compounds, Carbides, Cobalt compounds, Grain size and shape; Ion beam assisted deposition, Ion beams, Ions, Nanostructured materials, Phase composition, Structure (composition), Substrates, Textures, Titanium compounds, Cathodic arc deposition, Deposition conditions, Duty-cycle, Grainsize, Microstructure-texture, Pulsed bias, Substrate bias, Ti-Al-N, Tix-1alxn coating, WC Co cemented carbide substrate, Surface roughness
National Category
Manufacturing, Surface and Joining Technology
Research subject
Mechanical Engineering; Materials Engineering
Identifiers
URN: urn:nbn:se:kau:diva-99735DOI: 10.37904/nanocon.2023.4755Scopus ID: 2-s2.0-85191190712ISBN: 978-80-88365-15-0 (electronic)OAI: oai:DiVA.org:kau-99735DiVA, id: diva2:1864176
Conference
15th International Conference on Nanomaterials - Research and Application, NANOCON, Brno, Czech Republic, October 18-20, 2023.
Funder
Knowledge FoundationAvailable from: 2024-06-03 Created: 2024-06-03 Last updated: 2024-06-03Bibliographically approved

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Pinchuk, NataliiaFallqvist, MikaelKrakhmalev, Pavel

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