Green solvents (GSs) has gained significant attention in recent years due to their potential as safer and more sustainable alternatives to traditional organic solvents. Solvents are used in a wide range of applications, from industrial processes to everyday products. Solvent emissions and losses can have a significant impact on the environment and human health, which is why many initiatives are being undertaken to get rid of or switch to eco-friendly alternatives. A key area of green chemistry that led to the concept of "green" solvents is the development of alternative solvents that are less toxic and more environmentally friendly than traditional organic solvents. The advantages of using green solvents over conventional ones are their environmental friendliness, biocompatibility, biodegradability, and simplicity of preparation. Different sample preparation techniques have successfully utilized green solvents to offer a sustainable separation media for the extraction of a variety of inorganic and organic compounds which are crucial for research in environmental samples. Recent developments in green analytical chemistry (GAC) have focused on how to prepare and use samples using environmentally sustainable solvents. The current study covers the advance and currently used green solvents with an emphasis on environmentally friendly sample preparation methods. This review aims to briefly summarize the current state of knowledge about the use of green solvents particularly ionic liquids, deep eutectic solvents and switchable solvents (SSs) with the perspective of GAC in sample preparation methods.