Using membranes for CO2 capture has gained recent prominence in the global scientific community due to its lower capital cost and a quicker separation performance than the conventional separation methods. The membrane process features desirable properties, like compactness, energy efficiency, and environmental friendliness. Various polymeric and inorganic materials have been tested both as unique ingredients and blends to form CO2 separation membranes with a focus on increasing the performance but have had varying rates of success. For commercial viability, the membrane sector requires new techniques and testing materials to lower the cost of CO2 capture. Recently, thermally rearranged polymers, intrinsic microporous polymers, ionic liquid inclusion as fillers, and binary fillers have all emerged as novel trends, focusing on enhancing the working efficiency and sustainability of the membranes. This chapter explores the most recent advances in membrane technology and its future prospects as a sustainable solu ion towards carbon dioxide capture.