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Efficient Wide-Bandgap Mixed-Cation and Mixed-Halide Perovskite Solar Cells by Vacuum Deposition
University Valencia, ESP.
University Valencia, ESP.
University Valencia, ESP.ORCID iD: 0000-0002-1503-5965
Karlstad University, Faculty of Health, Science and Technology (starting 2013), Department of Engineering and Physics (from 2013).ORCID iD: 0000-0001-9606-3521
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2021 (English)In: ACS Energy Letters, E-ISSN 2380-8195, Vol. 6, no 2, p. 827-836Article in journal (Refereed) Published
Abstract [en]

Vacuum deposition methods are increasingly applied to the preparation of perovskite films and devices, in view of the possibility to prepare multilayer structures at low temperature. Vacuum-deposited, wide-bandgap solar cells based on mixed-cation and mixed-anion perovskites have been scarcely reported, due to the challenges associated with the multiple-source processing of perovskite thin films. In this work, we describe a four-source vacuum deposition process to prepare wide-bandgap perovskites of the type FA(1-n)Cs(n)Pb-(I1-xBrx)(3) with a tunable bandgap and controlled morphology, using FAI, CsI, PbI2, and PbBr2 as the precursors. The simultaneous sublimation of PbI2 and PbBr2 allows the relative Br/Cs content to be decoupled and controlled, resulting in homogeneous perovskite films with a bandgap in the 1.7-1.8 eV range and no detectable halide segregation. Solar cells based on 1.75 eV bandgap perovskites show efficiency up to 16.8% and promising stability, maintaining 90% of the initial efficiency after 2 weeks of operation.

Place, publisher, year, edition, pages
American Chemical Society (ACS), 2021. Vol. 6, no 2, p. 827-836
National Category
Materials Chemistry Physical Sciences Condensed Matter Physics
Research subject
Physics; Chemistry - Materials Science
Identifiers
URN: urn:nbn:se:kau:diva-83542DOI: 10.1021/acsenergylett.0c02445ISI: 000619803400063Scopus ID: 2-s2.0-85101039246OAI: oai:DiVA.org:kau-83542DiVA, id: diva2:1540159
Available from: 2021-03-26 Created: 2021-03-26 Last updated: 2022-05-25Bibliographically approved

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Hawash, ZaferMoons, Ellen

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Palazon, FranciscoHawash, ZaferMoons, EllenBolink, Henk J.
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