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Gas-solid reaction based over one-micrometer thick stable perovskite films for efficient solar cells and modules
Okinawa Institute of Science and Technology Graduate University, JPN.ORCID iD: 0000-0003-4743-6971
Okinawa Institute of Science and Technology Graduate University, JPN.ORCID iD: 0000-0002-7696-4901
Okinawa Institute of Science and Technology Graduate University, JPN.
Okinawa Institute of Science and Technology Graduate University, JPN.ORCID iD: 0000-0001-9606-3521
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2018 (English)In: Nature Communications, E-ISSN 2041-1723, Vol. 9, article id 3880Article in journal (Refereed) Published
Abstract [en]

Besides high efficiency, the stability and reproducibility of perovskite solar cells (PSCs) are also key for their commercialization. Herein, we report a simple perovskite formation method to fabricate perovskite films with thickness over 1 mu m in ambient condition on the basis of the fast gas-solid reaction of chlorine-incorporated hydrogen lead triiodide and methylamine gas. The resultant thick and smooth chlorine-incorporated perovskite films exhibit full coverage, improved crystallinity, low surface roughness and low thickness variation. The resultant PSCs achieve an average power conversion efficiency of 19.1 +/- 0.4% with good reproducibility. Meanwhile, this method enables an active area efficiency of 15.3% for 5 cmx 5 cm solar modules. The un-encapsulated PSCs exhibit an excellent T-80 lifetime exceeding 1600 h under continuous operation conditions in dry nitrogen environment.

Place, publisher, year, edition, pages
Nature Publishing Group, 2018. Vol. 9, article id 3880
National Category
Materials Engineering
Research subject
Materials Engineering
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URN: urn:nbn:se:kau:diva-83181DOI: 10.1038/s41467-018-06317-8ISI: 000445329000015PubMedID: 30250031OAI: oai:DiVA.org:kau-83181DiVA, id: diva2:1530231
Available from: 2021-02-22 Created: 2021-02-22 Last updated: 2023-03-28Bibliographically approved

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Hawash, Zafer

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Liu, ZonghaoQiu, LongbinHawash, ZaferJiang, YanOno, Luis K.Qi, Yabing
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