The role of zeolite structure and acidity in catalytic deoxygenation of biomass pyrolysis vapors Show others and affiliations
2015 (English) In: CLEAN, EFFICIENT AND AFFORDABLE ENERGY FOR A SUSTAINABLE FUTURE / [ed] Yan, J; Shamim, T; Chou, SK; Li, H, Elsevier, 2015, Vol. 75, p. 793-800Conference paper, Published paper (Refereed)
Abstract [en]
Catalytic upgrading of paddy husk was performed over 10-MR zeolites (MCM-22, ITQ-2 and ZSM-5) in a drop type fixed-bed reactor. This work investigated the role of structure and acidity of zeolites on pyrolysis-oil yield and degree of deoxygenation. Catalytic pyrolysis experiments were carried out at the catalyst/biomass ratio (0.05 -0.5) at temperature of 450 degrees C. The oil yield decreased by using catalyst and this decrease oil yield is attributed to catalytic cracking of bio-oil vapor on the catalyst. The route for deoxygenation of pyrolysis vapors was identified to be dehydration, decarboxylation and decarboxylation. ITQ-2 showed high degree of deoxygenation as compare to MCM-22 which is due to more accessible external active sites of ITQ-2. The organics yield in pyrolysis oil was highest with ZSM-5 in comparison with other zeolites. (C) 2015 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license
Place, publisher, year, edition, pages Elsevier, 2015. Vol. 75, p. 793-800
Series
Energy Procedia, ISSN 1876-6102 ; 75
Keywords [en]
Biomass, catalytic upgrading, zeolites, yield, deoxygenation
National Category
Chemical Engineering
Research subject Chemical Engineering
Identifiers URN: urn:nbn:se:kau:diva-75321 DOI: 10.1016/j.egypro.2015.07.126 ISI: 000361030001038 OAI: oai:DiVA.org:kau-75321 DiVA, id: diva2:1360773
Conference 7th International Conference on Applied Energy (ICAE, Abu Dhabi, U ARAB EMIRATES, MAR 28-31, 2015
2019-10-142019-10-142020-01-28 Bibliographically approved