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Lignin Recovery from Spent Alkaline Pulping Liquors Using Acidification, Membrane Separation, and Related Processing Steps: A Review
North Carolina State Univ, Dept Forest Biomat,.
University Jyvaskyla, Finland.
FPInnovations, Canada.
Natl Res Council Canada.
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2019 (English)In: BioResources, E-ISSN 1930-2126, Vol. 14, no 1, p. 2300-2351Article in journal (Refereed) Published
Abstract [en]

The separation of lignin from the black liquor generated during alkaline pulping is reviewed in this article with an emphasis on chemistry. Based on published accounts, the precipitation of lignin from spent pulping liquor by addition of acids can be understood based on dissociation equilibria of weak acid groups, which affects the solubility behavior of lignin-related chemical species. Solubility issues also govern lignin separation technologies based on ultrafiltration membranes; reduction in membrane permeability is often affected by conditions leading to decreased solubility of lignin decomposition products and the presence of colloidal matter. Advances in understanding of such phenomena have potential to enable higher-value uses of black liquor components, including biorefinery options, alternative ways to recover the chemicals used to cook pulp, and debottlenecking of kraft recovery processes.

Place, publisher, year, edition, pages
NORTH CAROLINA STATE UNIV , 2019. Vol. 14, no 1, p. 2300-2351
National Category
Materials Engineering Paper, Pulp and Fiber Technology
Research subject
Materials Engineering
Identifiers
URN: urn:nbn:se:kau:diva-71492ISI: 000459494400158OAI: oai:DiVA.org:kau-71492DiVA, id: diva2:1296215
Available from: 2019-03-14 Created: 2019-03-14 Last updated: 2024-07-04Bibliographically approved
In thesis
1. On the resource efficiency of kraft lignin extraction
Open this publication in new window or tab >>On the resource efficiency of kraft lignin extraction
2021 (English)Licentiate thesis, comprehensive summary (Other academic)
Abstract [en]

Lignin is regarded as a promising raw material for the production of biobased products, such as chemicals, materials and fuels, and will most probably be a key component in future lignocellulosic biorefineries.

This thesis examines the lignin extraction process in a kraft pulp mill, the technologies that are available for this purpose, and the impact made on the mill. Several different kraft lignin extraction processes and technologies are currently available and are basically linear: chemicals are brought from outside the mill and introduced into the process and the mill balance. Depending on their origin, the addition of these chemicals will affect the mill to a lesser or greater degree, both economically and environmentally. A conceivable way of reducing the impact made on the mill´s balance would be the in-house production of the chemicals used, sulphuric acid and CO2, which takes a more sustainable circular approach.

The results obtained show that utilisation of existing process streams in the mill as a source of chemicals could be a way of not only reducing these impacts but also making lignin extraction more sustainable. Internal production of sulphuric acid is possible and could generate a substantial amount for use as replacement of the fresh sulphuric acid needed for the lignin extraction process; CO2 is available in large quantities in the mill and could be captured and used for lignin extraction.

Place, publisher, year, edition, pages
Karlstads universitet, 2021. p. 48
Series
Karlstad University Studies, ISSN 1403-8099 ; 2021:1
National Category
Chemical Engineering
Research subject
Chemical Engineering
Identifiers
urn:nbn:se:kau:diva-81473 (URN)978-91-7867-172-4 (ISBN)978-91-7867-177-9 (ISBN)
Presentation
2021-01-29, 9C203 Nyquistsalen, Karlstads universitet, Karlstad, 10:15 (English)
Opponent
Supervisors
Available from: 2021-01-17 Created: 2020-11-25 Last updated: 2021-01-17Bibliographically approved

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