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Characterization of an unusual adsorption behavior of racemic methyl-mandelate on a tris-(3,5-dimethylphenyl) carbamoyl cellulose chiral stationary phase
Karlstad University, Faculty of Technology and Science, Department of Chemistry and Biomedical Sciences.ORCID iD: 0000-0002-8943-6286
Karlstad University, Faculty of Technology and Science, Department of Chemistry and Biomedical Sciences.ORCID iD: 0000-0003-1819-1709
Uppsala University Analytisk Kemi.
Karlstad University, Faculty of Health, Science and Technology (starting 2013), Department of Engineering and Chemical Sciences.ORCID iD: 0000-0002-7123-2066
2011 (English)In: Journal of Chromatography A, ISSN 0021-9673, E-ISSN 1873-3778, Vol. 1218, no 38, p. 6688-6696Article in journal (Refereed) Published
Abstract [en]

An interesting adsorption behavior of racemic methyl mandelate on a tris-(3,5-dimethylphenyl)carbamoyl cellulose chiral stationary phase was theoretically and experimentally investigated. The overloaded band of the more retained enantiomer had a peculiar shape indicating a type V adsorption isotherm whereas the overloaded band of the less retained enantiomer had a normal shape indicating a type I adsorption behavior. For a closer characterization of this separation, adsorption isotherms were determined and analyzed using an approach were Scatchard plots and adsorption energy distribution (AED) calculations are combined for a deeper analysis. It was found that the less retained enantiomer was best described by a Tóth adsorption isotherm while the second one was best described with a bi-Moreau adsorption isotherm. The latter model comprises non-ideal adsorbate–adsorbate interactions, providing an explanation to the non-ideal adsorption of the more retained enantiomer. Furthermore, the possibility of using the Moreau model as a local model for adsorption in AED calculations was evaluated using synthetically generated raw adsorption slope data. It was found that the AED accurately could predict the number of adsorption sites for the generated data. The adsorption behavior of both enantiomers was also studied at several different temperatures and found to be exothermic; i.e. the adsorbate–adsorbate interaction strength decreases with increasing temperature. Stochastic analysis of the adsorption process revealed that the average amount of adsorption/desorption events increases and the sojourn time decreases with increasing temperature.

Place, publisher, year, edition, pages
2011. Vol. 1218, no 38, p. 6688-6696
Keywords [en]
Adsorption energy distribution, Chiral separation, Moreau adsorption model, Perturbation peak method, Stochastic modeling, Tóth adsorption model
National Category
Analytical Chemistry
Identifiers
URN: urn:nbn:se:kau:diva-15246DOI: 10.1016/j.chroma.2011.07.064ISI: 000295432700014OAI: oai:DiVA.org:kau-15246DiVA, id: diva2:562025
Note

ID - 457

Available from: 2012-10-23 Created: 2012-10-23 Last updated: 2017-12-07Bibliographically approved

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Publisher's full texthttp://www.sciencedirect.com/science/article/pii/S0021967311010740Electronic full text

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Enmark, MartinSamuelsson, JörgenFornstedt, Torgny

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